The evolution and extinction of different animals at particular times in the past can be used to roughly indicate the age of deposits in which a bone was buried. For example the discovery of hippopotamus bones at Mother Grundy's Parlour, Creswell Crags, indicates the presence of Interglacial cave deposits laid down between 130,000 and 110,000 years ago. Bone which is less than 40,000 years old can also be radiocarbon dated. Dating bone which is cut marked directly dates the presence of people.
Explore the hippopotamus bones found in Mother Grundy's Parlour
What is radiocarbon?
Radiocarbon dating is a scientific method of dating which can be used on any material which came from a living source within the last 40,000 years. Such organic materials include things often found by archaeologists such as bone, antler, ivory, teeth and charcoal.
Radiocarbon or carbon-14 (C14) is a radioactive isotope of carbon. It is produced in the upper atmosphere by radiation from the sun. It is absorbed by plants with carbon dioxide from the air. Animals eat the plants and, in turn, absorb C14 from them.
How is radiocarbon useful for dating ?
When plants and animals die they stop taking in C14 and, the C14 they have absorbed begins radioactive decay. After 5730 years only half of it will be left. This decreases to 25% after 11,460 years, 12.5% after 17,190 years, 6.25% after 22,290 years and so on. After 37,000 years less than 1% of the original radiocarbon will remain. Eventually, in about 70,000 years, it will all be gone. Given this known rate of decay, it is possible to calculate the age of an organic material by measuring the amount of radiocarbon remaining in a sample from it.
How is radiocarbon measured?
When radiocarbon was first discovered it was measured by the strength of its radioactive signal. This signal gets weaker with age and becomes increasingly difficult to detect causing uncertainties about the results, especially those from older samples. Now, most radiocarbon laboratories use accelerator mass spectrometry (AMS) to measure the amount or mass of C14 left in a sample. This allows older and smaller samples to be dated more accurately.
How does the accelerator work?
To separate C14 from all the other molecules, the sample is subjected to a massive charge of 2 million volts. This accelerates them to energy levels high enough to allow their tiny amount to be detected and measured by a meter called the mass spectrometer.
What can be dated?
In theory, the remains of anything that has lived within the last 40,000 years can be dated by the radiocarbon method. At Creswell this includes bones, teeth, antler and charcoal. The most useful samples are those which come from a known position and help to date other things by their association. For example, a piece of bone or a tooth which can be identified as coming from a particular species of animal and which also shows cut marks made by stone tools, may provide an age not just for the local presence of that species but for human activity in a known part of the site. View an example from Creswell.
What should not be dated?
Misleading dates can be obtained if a bone has been coated with a preservative or repaired with glue made from organic materials. These can add new or old radiocarbon to the sample and may make the dates too young or too old. This can be a problem when selecting samples from museum collections and old excavations as at Creswell. However, careful sampling and sample preparation can overcome this difficulty. This is not the case with charcoal. Charcoal fragments are often small and light. They move around and get mixed easily within a site. Using several small pieces of charcoal to make a sample big enough for dating may combine fragments of quite different ages so the 'date' which is obtained is just an average of the sample rather than an actual age. This can be misleading rather than helpful.
How do we know if a radiocarbon date is right?
There are two ways to check radiocarbon dates. It is possible to date things for which historians know the right answer, for example, wood from the coffin of a pharoah whose date of death is known from other sources. However, such right answers do not exist for much older, prehistoric things. The radiocarbon age estimates then have to be checked against other methods. The most important of these is tree ring counting or dendrochronology. Trees produce a new growth ring for every year of their life. These will vary in thickness according to the weather conditions. By matching up the ring patterns from tree to tree it is possible to count back through time. Samples of wood of known age can then be dated to check the radiocarbon method. When this was first done it showed that radiocarbon dates were coming out too young because the amount of radiocarbon available in the air had varied. Consequently, radiocarbon dates have to be corrected or 'calibrated' into real calendar years.
What might affect the amount of radiocarbon in a sample?
The amount of radiocarbon in the air has not always been the same. It has changed in response to solar activity (sunspots), changes in the earth's magnetic field, climatic change and, in more recent times, as a result of human activity. Detecting how much effect these variations have on radiocarbon dates is an important area of research. Which will help to improve the accuracy of the calibrations. Although long lived trees such as the Californian bristlecone pine can take us back some 10,000 years, variations in the radiocarbon supply during the climate changes of the Ice Ages are much older. New research on stalagmite (flowstone) suggests that there were dramatic variations in radiocarbon concentrations beyond 20,000 years ago and will provide better adjustment of age estimates. Similarly, the annual layers of sediment or varves laid down on the bottom of lakes can go much further back than the end of the Last Ice Age as at Lake Suigetsu in Japan, where a radiocarbon calibration curve back to 45,000 years ago has been established. However, for the moment it is best to regard radiocarbon results as age estimates rather than exact dates.
What is the difference between calibrated and uncalibrated dates?
Dates in radiocarbon years are quoted using the lower case letters bp (before present). Present is taken as 1950 AD. To allow for some imprecision in their measurement, a margin of error of plus or minus a certain number of years is quoted. For example, if a date is given as 10,000 +/- 150 bp, this means there is a 66.6% chance that its age lies between 9,850 and 10,150 radiocarbon years. A radiocarbon date calibrated to calendar years is given with the upper case letter BP or BC, without the +/- to indicate standard deviation.